Capping agent promoted oxidation of gold nanoparticles: cetyl trimethylammonium bromide.

نویسندگان

  • Blake J Plowman
  • Kristina Tschulik
  • Neil P Young
  • Richard G Compton
چکیده

Capping agents, key for nanoparticle stability, may hugely influence chemical behaviour. We show that differently capped gold nanoparticles, with either citrate or cetyl trimethylammonium bromide (CTAB) capping agents, show qualitatively different electron transfer properties. Specifically through cyclic voltammetry and nanoimpact studies the CTAB promoted dissolution of gold nanoparticles is shown, highlighting the active role which capping agents can play in charge transfer.

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عنوان ژورنال:
  • Physical chemistry chemical physics : PCCP

دوره 17 39  شماره 

صفحات  -

تاریخ انتشار 2015